Chemical Emulsification Of Nigerian Heavy Oil
Abstract
The inviability of the conventional methods of reducing the heavy oil viscosity by heating or dilution with organic solvent or light crude that is in short supply or uneconomic, and transporting the mixture over a long distance prompted this study. The work investigated the in situ enhanced recovery by modifying the intrinsic high viscosity of Agbabu Heavy Oil 2,166cP and specific gravity 1.0874 at ambient temperature through chemical means and the study of the stability of o/w emulsion produced. A 23 Yates’ factorial experimental design analysis was carried out on the sample to determine the chemical formulation and combinations that will yield optimum o/w emulsion from NaOH concentration (0.1-1.0M), NaCl concentration (1-4wt %), and temperature (30-80oC). Optimum yield of Agbabu heavy oil in the form of concentrated oil-in-water emulsion was produced at 30oC temperature, 0.1M NaOH concentration, and 1wt% NaCl concentration indicating the effect of their levels on emulsion formation and viscosity. The investigated o/w emulsion behaved almost Newtonian with viscosity ranges from 31.07 to 372.86cP depending on the rate of shear.
References
Adegoke, O.S., and Ibe, E.C., “The tar Sand and Heavy Crude resources of Nigeria” 2nd. International Conference on Heavy Crude and Tar Sand, Caracas, Venezuela, 1982.
Adewusi, V.A.,”Bitumen Emulsification and Microemulsion Phase Behaviour in Bitumen-Caustic Systems” Energy Sources, II (4): 279-292, 1989.
Bello, O.O., Sonibare, J.A., Ademodi, B.T., Macaulay, S.R.A., and Adebiyi, F. M., “Environmental Impact Assessment of Commercial Tar Sands Development in Nigeria” North American Free Trade Agreement Journal, 54(11): 417 – 423, 2003.
Burris, D.R., “Dual Polarity Oil Dehydration” Petroleum Engineer International, 1977.
Campbell, T.C., “A comparison of sodium orthosilicate and sodium hydroxide for alkaline water flooding” Paper SPE 6514 presented at the 1977 SPE California regional Meeting, Bakersfield, 1977.
Carrigy, M.A., “Thermal recovery from tar sands” Journal of Petroleum Technology, 2149-2156, 1983.
Delmar, R.S., “Asphalt emulsion technology” Transport Research Circular E-C 102: 2-15, 2006.
Dickinson, E., “Thermodynamic Aspects of Emulsion Phase Inversion” Journal of Colloid Interface Science, 87: 416-423, 1982.
Hobson, G.D., and Pohl, M., “Modern Petroleum Technology” 4th Edition, Applied Science Publishers, New York, 1973.
Kessick, M.A., and St. Dennis, C.E., “In-situ formation of oil-in-water emulsion from bituminous oil deposits” US Patent 1(136): 542, 1982.
Mao, M. L., and Marsden, S. S., “Stability of Concentrated Crude Oil-in-Water Emulsions as a Function of Shear Rate, Temperature and Oil Concentration” Journal of Canadian Petroleum Technology, 16(2): 54-59, 1977.
McClaflin, G.G., Clark, C.R., and Sifferman, T.R., “The Replacement of Hydrocarbon Diluent with Surfactant and Water for the Production of Heavy, Viscous Crude Oil” Journal of Petroleum Technology, 34(10): 2258-2264, 1982.
Montgomery, D. C., “Design and analysis of experiments” 5th Edition, John Wiley & Sons Inc. New York, 2001.
Narsimhan, G., and Goel, P., “Drop coalescence during emulsion formation in a high-pressure homogenizer for tetradecane-in-water emulsion stabilized by sodium dodecyl sulfate” Journal of Colloid and Interface Sciences, 238: 420-432, 2001.
Norato, M.A., Tsouris, C., and Tavlarides, L. L., “Phase Inversion Studies in Liquid-Liquid Dispersions” Canadian Journal of Chemical Engineering, 76: 486-494, 1998.
Reisberg, J., and Dosher, T.M., “Interfacial Phenomena in Crude-Oil-Water Systems” Producers Monthly, 45-50, 1956.
Rousseau, G., Zhou, H., and Hurtevent, C., “Calcium Carbonate and Naphthenate Mixed Scale in Deep-offshore Fields” In SPE Oilfield Scale Symposium. Society of Petroleum Engineers Inc., Aberdeen, UK, 2000.
Simon, R., and Poynter, W.G., “Down-Hole Emulsification for Improving Viscous Crude Production” Journal of Petroleum Technology, 20(12): 1349-1353, 1968.
Sloan, A., Ingham, R., and Mann, W.L., Report No 76, First International Conference on the Future of Heavy Crude and Tar Sands, UNITAR, Long Beach, California, U.S.A., 1979.
Tobin, T., and Ramkrishna, D., “Coalescence of Charged Droplets in Agitated Liquid- Liquid Dispersions” American Institute of Chemical Engineering Journal, 38(8), 1199-1205, 1992.
Trujillo, E.M., “The static and dynamic interfacial tension between crude oils and caustic solutions” Society of Petroleum Engineering Journal, 645-656, 1983.
Urquhart, R.D., “Heavy Oil Transportation: Present and Future” Journal of Canadian Petroleum Technology, 25(2): 68-71, 1986.
Yeo, L.Y., Matar, O.K., Perez de Ortiz, E.S., and Hewitt G.F., “Phase Inversion and Associated Phenomena” Multiphase Science and Technology, 12: 51-116, 2000