Eco-Friendly Inhibitors for Erosion-Corrosion Mitigation of API-X65 STEEL in CO2 Environment

  • O.O. Ige Department of Materials Science and Engineering, Obafemi Awolowo University, Nigeria.
  • M.D. Shittu Department of Materials Science and Engineering, Obafemi Awolowo University, Nigeria.
  • K.M. Oluwasegun Department of Materials Science and Engineering, Obafemi Awolowo University, Nigeria.
  • O.E. Olorunniwo Department of Materials Science and Engineering, Obafemi Awolowo University, Nigeria.
  • L.E. Umoru Department of Materials Science and Engineering, Obafemi Awolowo University, Nigeria.
Keywords: Erosion-corrosion, Inhibitors, Multiphase system, Steel, Rotating cylinder electrode, scanning electron microscopy

Abstract

The study of chemical mitigation of erosion-corrosion of API-X65 Steel in a multiphase system containing brine, CO2 gas, and sand at different shear stresses with two eco-friendly inhibitors are reported. The inhibitors investigated are a commercial grade synthetic product and a natural inhibitor (Aloe vera). The mass loss, linear polarization, and scanning electron microscopy techniques were investigated. The results obtained show that both inhibitors maybe useful in oil and gas industry, the synthetic inhibitor have quantifiable advantage over the natural inhibitor. From the results obtained these inhibitors are expected to have credible technical performance and as such reduce considerably the adverse effects on health, safety, and environmental factors associated with inhibition in oil and gas industries.

Author Biographies

O.O. Ige, Department of Materials Science and Engineering, Obafemi Awolowo University, Nigeria.

Department of Materials Science and Engineering,

Obafemi Awolowo University, Nigeria.

M.D. Shittu, Department of Materials Science and Engineering, Obafemi Awolowo University, Nigeria.

Department of Materials Science and Engineering,

Obafemi Awolowo University, Nigeria.

K.M. Oluwasegun, Department of Materials Science and Engineering, Obafemi Awolowo University, Nigeria.

Department of Materials Science and Engineering,

Obafemi Awolowo University, Nigeria.

O.E. Olorunniwo, Department of Materials Science and Engineering, Obafemi Awolowo University, Nigeria.

Department of Materials Science and Engineering,

Obafemi Awolowo University, Nigeria.

L.E. Umoru, Department of Materials Science and Engineering, Obafemi Awolowo University, Nigeria.

Department of Materials Science and Engineering,

Obafemi Awolowo University, Nigeria.

References

Chen, H.J., and Chen, Y. ‘Environmentally friendly inhibitors for CO2 corrosion’, CORROSION 2002, NACE 02300, Houston, Texas, 2002.
Dalayan, E., Johar, T., Shadley, J.R. and Shirazi, S.A. ‘Hydrodynamic correlations between pipe flow and rotating cylinder electrode (RCE) for oilfield corrosion – some insights’, Houston, NACE International, CORROSION/95, paper no. 117, 1995.
Efird, K.D. Wright, E.J. Boros, J.A. and Hailey, T.G. ‘Correlation of steel corrosion in pipe flow with jet impingement and rotating cylinder tests’, Corrosion, 49 (12): 992-1003, 1993.
Gabe, D.R., and Walsh, F.C. ‘The rotating cylinder electrode: A review of development’, Journal of applied electrochemistry, 13 (1): 3-21, 1983.
Hu, X. Barker, R. Neville A. and Gnanavelu, A. ‘Case study on erosion-corrosion degradation of pipework located on an offshore oil and gas facility’, Wear, 271: 1295-1301, 2011.
Obeyekesere, N.N., Naraghi, A.R. and Zhou, S. ‘Further advances of environmentally friendly corrosion inhibitors for CO2 corrosion in North Sea oil fields’ CORROSION 2002, Houston, Texas, NACE 02415, 2002.
Janine Killars, and Pat Finley. ‘Move to environmentally acceptable products: How the OSPARCOM legislation affects the introduction of new products’, Symposium on oilfield chemistry, SPE 65044, Houston, Texas, 2001.
Jiang, X. Zheng, Y.G. and Ke, W. ‘Effect of flow velocity and entrained sand on inhibitor performances of two inhibitors for CO2 corrosion of N80 steel in 3% NaCl solution’, Corrosion science, 47: 2636-2658, 2005.
Linter, B.R. and Burstein, G.T. ‘Reactions of pipeline steels in CO2 solutions’, Corrosion science, 41: 117-139, 1999.
McLaury, B.S., Shiraz, S.A., Shadley, J.R., and Rybick, E.F. ‘Parameters affecting flow accelerated erosion and erosion-corrosion’, NACE International, NACE 95120, 1995.
Musa, A.Y. Kadhum, A.H. Mohamad, A.B. Daud, A.R. Takriff, M.S. Kamarudin, S.K. and Muhamad, N. ‘Stability of layer forming for corrosion inhibitor on mild steel surface under hydrodynamic conditions’, Int. J. Electrochem. Sci. 4: 707-716, 2009.
Neville, A. and Wang, C. ‘Erosion-corrosion mitigation by corrosion inhibitors – An assessment of mechanisms’, Wear, 267: 195-203, 2009.
Neville, A. and Wang, C. ‘Study of the effect of inhibitor on erosion-corrosion in CO2-saturated condition with sand’, SPE projects, facilities and construction, SPE 114081, 1-10, 2009
Nesic, S. Solvi, G.T. and Enerhaug, J. ‘Comparison of the rotating cylinder and pipe flow test for flow-sensitive CO2 corrosion’, Corrosion, 51(10) : 773-787, 1995.
Obeyesekere, N., Narghi, A., Dharma Abayarathna, Prasad, R., Montgomeric, H. ‘Environmentally friendly corrosion for CO2 corrosion in north sea’, Houston, Texas, NACE, CORROSION 2000, Paper 00020, 2000.
Ramachandran, S., Ahn, Y.S., Batrip, K.A., Jovancicevic, V., and Basset, J. ‘Further advances in the development of erosion corrosion inhibitors’, in: CORROSION/2005, NACE International, Houston, Texas, NACE 05292, 2005.
Schmitt, G. ‘Drag reduction by corrosion inhibitors – A neglected option for mitigation of flow induced localized corrosion’, Materials and Corrosion, 52 (5): 329-343, 2001.
Silverman, D.C. ‘ Rotating Cylinder Electrode – Geometry relationships for prediction of velocity – sensitive corrosion’, Corrosion, Vol 44 (1: 42, 1987.
Taj, S. Papavinasam, S. and Revie, R.W. ‘Development of green inhibitors for oil nd gas applications’ CORROSION 2006, Houston, Texas, NACE 06656, 2006.
Wang, C., Neville, A., Ramachandran, S. and Jovancicevic, V. ‘Alleviation of erosion-corrosion damage by liquid-sand impact through use of chemicals’, Wear, 258, 649-658, 2005.
World Health Organizations. ‘Aloe vera gel: in WHO monographs on selected medicinal plants’ Volume 1, World Health Organization, Geneva, pp 43-49, 1999
Published
2012-11-01
How to Cite
Ige, O., Shittu, M., Oluwasegun, K., Olorunniwo, O., & Umoru, L. (2012). Eco-Friendly Inhibitors for Erosion-Corrosion Mitigation of API-X65 STEEL in CO2 Environment. Ife Journal of Technology, 21(2), 43-48. Retrieved from https://ijt.oauife.edu.ng/index.php/ijt/article/view/107